The lecturers will browse the different aspects of the synthesis of bulk molecular materials and bottom-up strategies towards the corresponding molecular nanoobjects. This approach is based on the use of well-defined precursors and a good control of the conditions in which they react together in order to master the topology/dimensionality, size/nuclearity, shape and dispersity of the bulk materials and nanoobjects. A special attention will be paid to their characterization using single-crystal X-ray diffraction and to their magnetic and electrochemical properties.
Content
Molecular Magnetism
Prerequisites, a quick reminder…
Interacting spins: The Kahn’s model
Multifunctional Molecule-based Magnets
Processing of Molecule-based Magnets
Photoresponsive molecular systems
Based on photoinduced energy transfer
Based on charge separation state
Application in redox photocatalysis
Application in molecularsensor
Based on photochromic units
Single-Crystal X-Ray diffraction
Crystal
RX-materials Interactions
Diffracted intensity
Apllication: structure resolution
Prerequisites
Synthesis: Basis in coordination and supramolecular chemistry including ligand design and synthesis, thermodynamic of complexes.
Properties and techniques: oxido-reduction properties, optical properties of complexes (Tanabe-Sugano diagrams, luminescence properties), magnetic properties of the single ion (Van Vleck and Curie laws, Zero-Field Splitting, Spin Cross-Over), knowledge on powder X-ray diffraction
Published on April 11, 2019 Updated on April 23, 2021
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